One-pot synthesis and characterization of high-quality CdSe/ZnX (X=S, Se) nanocrystals via the CdO precursor

نویسندگان

  • Guo-Wei Huang
  • Chun-Yen Chen
  • Kun-Chan Wu
  • Moawia O. Ahmed
  • Pi-Tai Chou
چکیده

We report on the synthesis of CdSe/ZnX (X=S, Se) core/shell quantum dots from the CdO precursor through a convenient, one-pot approach. The defocusing stage (i.e., Ostwald Ripening) can be finely controlled to prepare nearly monodispersive core/shell quantum dots. The resulting particles have been characterized by their corresponding optical properties, energy dispersive spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy and powder XRD. This method is highly reproducible, and quantum efficiencies as high as 0.7 can be achieved. r 2004 Elsevier B.V. All rights reserved. PACS: 81.05.Dz; 79.60.Jv; 81.65.Rv; 81.10.Dn

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Formation of high-quality CdTe, CdSe, and CdS nanocrystals using CdO as precursor.

High-quality colloidal semiconductor nanocrystals are nanometer-sized, single crystalline fragments of the corresponding bulk crystals, which have well-controlled size and size distribution and are dispersible in desired solvents/media. Recently, semiconductor nanocrystals are of great interest for both fundamental research and technical applications,1-8 due to their strong size dependent prope...

متن کامل

Using a bithiazole complex as precursor to synthesis of CdO-CdS nanocomposite via direct thermal decomposition

A new tris-chelate Cd(II) complex, [Cd(DADMBTZ)3](ClO3)2 has been successfully synthesized and characterized by IR, 1H, 13C NMR spectroscopy, elemental analysis and single crystal X-ray determination. The thermal behavior, UV-Vis and fluorescence spectra of compound were studied. In reaction with DADMBTZ, Cadmium (II) forms a tris-chelate complex with nearly C3 symmetry for coordination polyhed...

متن کامل

Cl-capped CdSe nanocrystals via in situ generation of chloride anions.

Halide ions cap and stabilize colloidal semiconductor nanocrystal (NC) surfaces allowing for NCs surface interactions that may improve the performance of NC thin film devices such as photo-detectors and/or solar cells. Current ways to introduce halide anions as ligands on surfaces of NCs produced by the hot injection method are based on post-synthetic treatments. In this work we explore the pos...

متن کامل

A Safer, Easier, Faster Synthesis for CdSe Quantum Dot Nanocrystals

www.JCE.DivCHED.org • Vol. 82 No. 11 November 2005 • Journal of Chemical Education 1697 Properties that vary with particle size are an important feature of nanoscale materials. CdSe quantum dot nanocrystals vary in color from green–yellow to orange–red and luminesce from blue to yellow, where shorter wavelength, higher energy, electronic transitions correspond to smaller crystal sizes. CdSe qua...

متن کامل

Using a bithiazole complex as precursor to synthesis of CdO-CdS nanocomposite via direct thermal decomposition

A new tris-chelate Cd(II) complex, [Cd(DADMBTZ)3](ClO3)2 has been successfully synthesized and characterized by IR, 1H, 13C NMR spectroscopy, elemental analysis and single crystal X-ray determination. The thermal behavior, UV-Vis and fluorescence spectra of compound were studied. In reaction with DADMBTZ, Cadmium (II) forms a tris-chelate complex with nearly C3 symmetry for coordination polyhed...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2004